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Shadow is the main villain in Yes! Pretty Cure 5: Kagami no Kuni no Miracle Daibouken!. In it, he steals the magical crystals of the Mirror Kingdom, thus destroying almost everything and everyone there, with Migirin and Hidarin being the exceptions. To make his dream of ruling all of worlds come true, he also attempts to take the Dream Collet. He creates the Dark Pretty Cure 5 by using the Mirror Kingdom's crystals to do so.
Yes! Pretty Cure 5: Kagami no Kuni no Miracle Daibouken!
Sometime before the movie starts he has conquered the mirror kingdom and stolen their crystals. He has also imprisoned all the residents by encasing them in crystals save Hidarin and Migirin who he is blackmailing into being his servants. He schemes to steal the dream collette and to use it to grant his wish of ruling all the worlds. To this end he creates Dark Pretty Cure 5 and sends out Hidarin and Migirin to steal it telling the duo that he will free all their friends if they do so. In reality this is all a trick and he is eventually defeated by the real Pretty Cure and the Mirror Kingdom is restored.
Pretty Cure All Stars DX 3: Mirai ni Todoke! Sekai wo Tsunagu☆Niji-Iro no Hana
She also appears in the third Pretty Cure All Stars movie. in this he is sick waiting an is going to look for the prism flower himself, using his mirrors. but in the end all the fairies stop him by using the miracle lights and he is purified.