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This, of course, is not enough to qualify her as a villain, despite its obvious hazards to the student bodies well-being, her role as a minor villain does not occur until she has Jimmy help her to arrange a "date" with Mr. Watts: the school chemistry teacher.
Edna has Jimmy collect several items, including a sedative, which she uses on the unfortunate Mr. Watts - although played as black comedy it is heavily implied Edna date-rapes Mr. Watts and has Jimmy aid her (though Jimmy was really only in the scheme for the money (as he often shifted between Chaotic Good to just plain Neutral).
Ultimately Edna gets away with this and continues to work at the school alongside many other equally corrupt staff, during the mission she also offered to "do worse" than spit in Mr. Hattrck's food for Jimmy as a reward: showing not even adults are safe from her when the mood suits her.