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Demon King Psycho is the ruler of the Madou crime syndicate and the main antagonist of Space Sheriff Sharivan. He later returns as the ultimate antagonist of the Super Hero Taisen Z movie.

History

Space Sheriff Sharivan

Though Psycho was immobile at first, he eventually uses his fully mobile cyborg Psychorror as an extension of himself, armed with twin swords. When Sharivan and Gavan enter his fortress, they discover that he uses two bodies at once. Sharivan destroys his immobile self while Gavan simultaneously destroys his second body.

Kamen Rider × Super Sentai × Space Sheriff: Super Hero Taisen Z

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Demon King Psycho in Super Hero Taisen Z

Strategist Reider revives Psycho from the Space Shocker fortress by using his magic and use its energy to complete the Demon King's resurrection. The resultant explosion provides enough power for it, before Reider perishes, just to later return as Space Reider, bringing several other monsters to the fight.

Psycholon is also overcome by the energy surge and is put under Madou's control as well. When Yoko calls out for Psycholon and it manages to break free from Psycho's control, the monster is ultimately destroyed by a robot formed by the Kyorugers' Kyoryuzin and Kamen Rider Wizard's WizarDragon combined.

           Super Hero Taisen Villains

Shocker-Zangyack Alliance
Dai-Shocker
Leader: Narutaki/Doktor G
Commanders: Apollo Geist | General Shadow | General Jark | General Black | Shadow Moon | Doras | N-Daguva-Zeba | El of the Ground | Orphnoch King | Joker Undead | Nurikabe | Gryllus Worm | Bat Fangire | Alligator Imagin | Llumu Qhimil | Weather Dopant | Mezool
Kaijin: Scorpion Man | Ghoster | Isoginjaguar | KomaThunder | Tiger-Roid | Cyborg Soldier Level 2 | Go-Gadoru-Ba | Go-Baberu-Da | Me-Garima-Ba | Go-Jaaza-Gi | Pantheras Luteus | Stellio Dextera | Brobajell | GuldMirage | Armadillo Orphnoch | Rhinoceros Beetle Orphnoch | Shell Undead | Tortoise Undead | Kasha | Musca Worm | Gecko Imagin | Bat Imagin | Mole Imagin | Medusa Legendorga | Warthog Fangire | Taurus Ballista | Cockroach Dopant | Spider Dopant | Kuwagata Yummy | Uni-Armadillo Yummy
Footsoldiers: Shocker Combatmen | Destron Combatmen | Dogma Fighters | Chaps | Makamou Ninja Group

Dai-Zangyack
Leader: Rider Hunter Silva
Commanders: Black Cross King | Hades God Cyclops | Hades God Drake | Hades God Sleipnir | Hades God Dagon | Yaiba of Darkness | Gai | Rei | Sea Fist Demon Rageku | Sanyo | Suugu | Long | Miranda | Rairaiken | Yogoshimacritein | Pollution President Batcheed | Doukoku Chimatsuri | Dereputa of the Meteor | Mons Drake of the Planet | Brajira of the Messiah | Deratsueigar | Zatsurig | Warz Gill | Ackdos Gill
Monsters: Shikabanen | Zodomas | Buramudo | Nanonanoda | Bowser | Yokubarido | Stargull | Almadon | Uorlian | Daiyarl | Shieldon | Vannain | Namono-Gatari of the Ortaurus Headder | Bari-Boru-Dara of the Uniberus Headder | Rō-O-Zā-Ri of the Hydrapan Headder | Chinomanako | Nunchaku Banki
Footsoldiers: Gormin | Sugormin | Dogormin

Demon King Psycho's Army
Space Shocker
Leader: Shadow Moon
Commanders: Space Ikadevil | Space Spider Man
Kaijin: Scorpion Man | Saboteguron | Ghoster | Zanjioh | Jaguarman | Girizames | Schwarian | Zu-Zain-Da | Sonorabuma | Buzzstinger Wasp | Arch Orphnoch | Tortoise Undead | Gecko Imagin | Pearlshell Fangire (Blue) | Bat Fangire | Beetle Fangire | Bat Dopant | Beast Dopant | Pteranodon Yummy | Kamakiri Yummy | Ika-Jaguar Yummy | Musca Zodiarts | Scorpion Zodiarts | Sagittarius Zodiarts | Skydain | Groundain
Footsoldiers: Shocker Combatmen | Chaps

Army of Resurrected
Leaders: Demon King Psycho | Space Reider
Members: Rhino Doubler | Lizard Doubler | Zan Vardo | Karateloid | Bulldozerloid | Parabolaloid 2 | Chief of Staff Damaras | Development Technical Officer Insarn | Dyrandoh | Stargull | Sneak Brothers | Dogormin | Doukoku Chimatsuri | Dayu Usukawa | Chinomanako | Nunchaku Banki | Long | Sanyo | Suugu | Sea Fist Demon Rageku | Furious Demon God Gai | Grand Beast Rei | Agent Abrella

Badan Empire
Leader: Generalissimo of Badan
Commanders: Ambassador Darkness | Kamen Rider Fifteen | Llumu Qhimil | General Shadow | High Priest Baraom | General Jark
Kaijin: Scorpion Man | Saboteguron | Ghoster | Zanjioh | Shiomaneking | Poison Lizard Man | Jaguarman | Girizames | Hiruchameleon | Ganikomol | Turtle Bazooka | Marshal Machine | Sword Master Birugenia | Schwarian | Doras | Garai | Suddendas | Bird Dopant | Kamakiri Yummy | Ika-Jaguar Yummy | Shocker Greeed | Chameleon Zodiarts | Libra Zodiarts | Arachne
Footsoldiers: Shocker Combatmen | Destron Combatmen | Combat-Roids | Chaps
Allies: General Schwarz

2015 Shocker
Leader: Great Leader of Shocker
Commanders: General Black | General Shadow | Marshal Machine | High Priest Darom | General Jark | Super Galaxy King | Schwarian | N-Gamio-Zeda | Lobster Orphnoch | Weather Dopant | Sagittarius Nova | Phoenix | Demushu | Roidmude 089
Kaijin: Garagaranda | Cheetahkatsumeri | Zanjioh | Shiomaneking | Poison Lizard Man | Poison Lizard Man | Girizames | Turtle Bazooka | Roidmude 057 | Roidmude 016 | Roidmude 076
Footsoldiers: Shocker Combatmen