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You're going down! Down, down, down!
~ Control Freak, meeting team Improbable

Control Freak is a one-shot fictional character from Phineas and Ferb episode "Out of Toon". She appears as a minor villain of the serial, but as the main antagonist of Phineas and Ferb's cartoon "Team Improbable", being the archenemy of the main heroes.

Out of Toon

Well, I would have super mind control and use telepathy and telekinesis to keep you super-dweebs under control with your lame-o superpowers.
~ Candace Flynn, creating Control Freak

When Phineas and Ferb showed their cartoon-studio to Candace and made two heroes based on them, Candace stated that she wants a character too. A super-strong version of herself, who able to use mind control, telepathy and telekinesis to keep cartoon version of Phineas and Ferb under her control. The boys then made Control Freak out of the example, and made her the main villains of the cartoon.

She first appears in the intro to "Team Improbable" cartoon, blasting the heroes out of the screen, as her name on the screen appears. She then challenges them to a duel, increasing her size. She successfully burns the team with her eye-lasers in a comical manner. However, she then gets tied by Rainbow (Isabella) and the others heroes. Gulchman (Buford) then taunts on her, gulching, and Hanuman Man (Baljeet) throwing a banana's skin under her feet, making her fall to the ground. Multi Man and Ferbguy (Phineas and Ferb) then tied her to the rocket and sent Control Freak to the space. 

However, Control Freak somehow managed to escape, only to be tied once again, this time way better. "Team Improbable" finishes with Control Freak absolutely immobilized and being sent to space on the rocket once again.

Trivia

           Phineas and Ferb Villains

Doofenshmirtz Evil Incorporated
Heinz Doofenshmirtz | Vanessa Doofenshmirtz | Norm | Gelatin Monster | Doofenshmirtz's Mecha | Rodrigo | Mindless Repulsive Pharmacists

L.O.V.E.M.U.F.F.I.N.
Aloyse Von Roddenstein | Dr. Bloodpudding | Dr. Diminutive | Orville Von Roddenstein | Professor Bannister | Bannister's Thugs | Me-Positive & Me-Negative | Dr. Killbot | Warehouse Goons

Doofenshmirtz Family (2nd Dimension)
Heinz Doofenshmirtz (2nd Dimension) | Charlene Doofenshmirtz (2nd Dimension) | Vanessa Doofenshmirtz (2nd Dimension) | Norm-Bots | Goozim | Animal-Borgs (Perry the Platyborg, Peter the Pandaborg & Pinky the Chihuahuaborg) | Tony Marzulo

Other Evil Scientists
Professor Destructicon | Dr. Gevaarlijk | Mitch | The Regurgitator | Esmeralda Poofenplotz | Khaka Peü Peü | Evil Carl (Evil Flynn-Fletcher Robots) | Mittington Random (The Klimpalooners) | Professor Mystery | Professor Parenthesis (Mecha-Fleas)

Time Shift
Jekyll Doofenshmirtz | Doofengung | Doofus Khan | Doofenshmirtz (1914) | Corn Colossus of Juatchadoon | Norm (1914) | Professor Von Doofenshmirtz | Pneumatic Pnorman | Darthenshmirtz | Darth Ferb | Candace's C.O. | Norm-3PO | Stormtrooper Candace | Stormtrooper Baljeet | Stormtrooper Buford

Fictional Characters
Control Freak | Smile Away Reformatory School Sergeant | Giant Buford | Malifishmertz | Meatlings | Lawn Gnorme | Keeper of the Bridge of Comprehension | Candace's Id | Worthington Dubois | Professor Nibbles | Der Kinderlumper

Misc.
Brobots | Suzy Johnson | Dennis the Rabbit | Busting Candace | Potato Gremlins | Liam McCracken | Morg | Peggy McGee