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During an encounter with Candy, the queen of the demons, Caitlin's morality is mocked and she suddenly transforms into a demon herself. She later attacks Quinn and intended to make him her first victim, but Quinn reminds Caitlin that she is one of the good guys, and she turns back to normal. Caitlin fights Candy and kills her by decapitating her with a sword.
Caitlin was played by Kelly Hu, who has also appeared on Arrow as China White.