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The Black Phoenixes were the Ikki's henchman during his rule in the Black Saints.
The black Phoenixes Saints help Ikki to steal the Sagittarius cloth, and each one take a part; four black phoenix was defeated by Seiya, Hyoga, Shiryu and Shun; the restant, leave the other parts of the cloth with Ikki, and never have seen again in the manga.
In the anime, one of these black saints, served Jango after he dominate the Death Queen Island and the Black Saints (including the blacks phoenixes), and the strongest Blacks Phoenixes (Ritahoa) fights against Ikki, but was defeated.
The Black Phoenix of the manga, only uses his brute force to fight against their enemies, and are not immortals.